Last letter = First Letter, min 3 syllable word chain

supernumerary

yellowish

haphazardly

yesterevening

gardyloo

orchestral

lycanthropic

chanticleer

retroactive

egalitarianism

Mesmerized

dodecahedron

Novocaine

embryo

otorhinolaryngology

yeastily

yellowhammer

redundancy

yellowish

hagiographer