Last letter = First Letter, min 3 syllable word chain

Narayanganj

The 6th largest city in Bangladesh, with a population of about 2 million. Named for the god Narayan and the river Ganges.

jurisdiction

nutria

atherosclerosis

serotonin

nonintersecting

Goliath

Hellenic

Consternation

Nickelodeon

nebula

amontillado

Original

lazier

revolutionizing

gullible

electroacoustic

cryogenic

circumnavigated

dividend