Last letter = First Letter, min 3 syllable word chain

Yugoslav

voluntary

yearningly

yohimbine

-“BB”-

Edwardian

Neptunian

Northumberland

derecho

-“BB”-

overfamiliarity

yardmaster

respectable

-“BB”-

edible

entropy

yuppifying

gastroenteritis

symbolism

menagerie

-“BB”-

entertainment

thermoregulated

Dasani