I watched a video on boiling ethanol in an electric kettle a while ago that informed me a lot on how these kettles worked–my assumption without knowing more about them, was boiling ethanol might not automatically shut off an electric kettle, ethanol boils at 78C, so it would never reach the boiling point of water, so if there was a temperature-based switch, in theory it would never trigger.
The video initially tries boiling 80-proof vodka, and it shuts off not long after it starts boiling. The presenter then notes that a 60/40 water/ethanol solution doesn’t actually boil at 78C, so it wasn’t a perfect test, he then tests again with a much more concentrated solution of ethanol, but it still turns off fairly quickly.
What is going on? At least the kettle he is presenting, has a little bimetallic switch in the base, the different metals expand at different rates as the temperature changes, causing the disc in the switch to buckle, which will close/open the switch. This of course does respond to changes in temperature, but it isn’t quite based on 212F/100C–as his testing shows. In fact, it makes perfect sense that it wouldn’t be based on 100C–100C is the boiling temperature at sea level, but not everyone lives at sea level. Instead, the switch is designed to fire at a temperature significantly lower than the boiling point of water. There is a small tube in the kettle, as the liquid in the kettle boils, vapor enters that tube and pressure in the kettle forces it down the tube, where it eventually pushes down around the bimetallic switch, this warm vapor eventually hits whatever the trigger point temperature the switch was designed at, which causes the switch to fire and turns off the heating element in the kettle. Since it is intended to fire at a lower temperature than the boiling point of water (significantly lower), even boiling something like ethanol that has a boiling point of 78C will also trigger it.
Now, why do these kettles have a minimum fill?
That seems to not be clearly answered upon any quick searching, but it is at least a popular answer that it is simply because the heating element is capable of overheating without enough water in the kettle to mediate. This was, supposedly, more of a concern with older style electric kettles that had “exposed” heating elements. The presenter of the YouTube video actually covers a second kettle, which at first he assumes doesn’t have the pressure vapor system because he couldn’t find the small metal pressure tube, but it’s actually built into the wall of the kettle and he eventually discovers it. That kettle does have a thermal switch thermal pasted to the bottom of the kettle’s base, which he speculates may be a sort of emergency kill switch if the heating element exceeds some safe operating temperature.
At least some people suggest that it is possible that if you go too far below the minimum fill line, the pressure required to push the warm vapor across the bimetallic switch won’t build up, and the kettle will never auto-shutoff. I haven’t seen that tested, but would be easy to test.
This is an example of the type of switch:
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