[quote=“DMC, post:15, topic:494830”]
It’s not that I don’t believe you, but do you have a cite for that order? Everything I’ve ever read said to get TA in order first, then pH, THEN Chlorine, as pH bounce will wreck havoc on everything you do otherwise.
QUOTE]
Cite? I don’t have my manuals handy, but I’ll see what I can find.
I am certified from both the the National Swimming Pool Foundation and the Lowry’s School of Pool and Spa Maintenance and have been working with pools and their chemistry for 30 years. I routinely work on pool systems much more complicated than your typical backyard pool so please remember I am trying keep it simple and easy.
I did assume that the TA was already in order (or close) so the OP merely needed add chlorine and to balance Ph and then perform routine maintenance.:smack:
You are correct that TA will minimize Ph bounce as you add chlorine, acid, etc., but my order is correct due to the varying Ph of the chemicals you will be adding and their effect on the preceding parameter as well as the latter.
Consider this.
Unstabilized chlorines, Calcium Hypochlorite (granulated) and Sodium Hypochlorite (liquid) are alkaline and have Ph’s of 11 and 13, respectively. Stabilized chlorines such as Dichlor, Trichlor are acidic and a Ph range from 2.8 to 6.8.
These can have a huge effect on Ph so you would want add them before balancing it.
When chlorine is at the desired level, you can then work on Ph. Now, for high Ph you add acid which lowers Ph but also lowers TA, alternatively for low Ph you add Sodium Carbonate which raises Ph and also TA.
Ok, Chlorine is at 2.0 ppm+, Ph is at 7.2-7.8, now you test and adjust TA to keep your water there.
Of course, this is a repetitive process and as you test, adjust, and retest it will become clear what the effects are.
As far as the Clorox (Sodium Hydrochlorite) is concerned, yes it is used quite commonly as a disinfecting agent mostly for indoor pools as it is the most readily available, has safer and easier handling and storage, but mostly it is relatively inexpensive as compared to the alternatives. It also is easier to use with chemical feeder systems. Pool chlorine bleach is usually sold at at 12% (10.8) active strength but you could still acheive 2.0 ppm (0.0002%) by diluting your household 6% solution.
One major problem with with Sodium Hydrochlorite is that it has a limited shelf life and can lose up to 50% of it’s active disinfecting strength in 3 months so you can’t stock up as you would with granulated.
Unfortunately, for outdoor use it needs to be stabilized against the sun’s ultraviolet rays or it breaks down quickly. This can be acheived by adding Isocyanuric Acid. The threshold for CYA is 25-50ppm.
If he is using Clorox and stabilizer one explanation for the white powder you describe could be “chlorine lock” or overstabilization since CYA will only leave the pool by physical means this occurs at levels of 100-150 ppm and it is precipitating to the bottom of the pool. The only solution is to drain the pool and dilute the water by a certain amount.
You should probably have a test done either by someone with a proper pool test kit or take a sample in which FTR I was not against but thought you might be able to avoid this.
Good Luck!