On that page, Randall Munroe in his hugely entertaining book “What If? 2” mentions the SDMB -
“What is the density of cocaine? I spent a while reading though a wonderfully earnest and citation-filled discussion of this question on the Straight Dope Message Board where several people tried to get to the bottom of this question…”
There is a user named xkcd that appears to have been quickly banned. In the few minutes I looked, I didn’t see an ATMB thread mentioning a reason. But then trying to search this board for mentions of a user named xkcd brings up a lot of erroneous results.
Quick bans suggest that it was a spammer. I could see someone borrowing the name for cred. I could also see it being a set of random four letters tried by a bot.
I doubt it was Randal Munroe himself. He’s too computer literate to have done something that would make him look like a spammer.
Elsewhere in that book he alludes to a message board thread about how much blood a human can drink without puking, but doesn’t mention which board. I think that might have been us, too.