The only thing leaked with passing regularity is pilots, some of which were mentioned above, or first episodes of new seasons of existing shows.
The reason for this is twofold. With pilots, they are usually made well in advance of the TV series going on-air. They’re usually made before the show is even “picked up” by the network, they’re kind of demo reels for a showrunner. They make the first episode for a set amount of money, and if the network is tickled by it, they ask for more episodes. Because there can be a long lag between the pilot being made and anybody having even heard of a show, there’s more time for illicit distribution.
The second reason is sort of a product of the first. When new shows are announced, networks usually send out DVDs to TV writers/bloggers with the pilots of the new shows, hoping the writers will speak favorably about it and drum up bigger numbers for the show’s primiere.
They also do this sometimes with the first episode of new seasons, so writers can see or talk about the direction the new season is going in. This seems to happen more with shows where each season is its own story, like Dexter.
Because these DVDs are being sent out to people so unscrupulous as TV “journalists,” it’s not surprising that they somehow end up online.
When it’s about time for new shows to come on, if you search the torrent sites for “preair” you’ll usually find a lot of them.
If the networks actually have a problem with this, they’re complete fools, as all it does is serve as publicity for a show. I based my decision to watch The Sarah Connor Whatevers because the pilot I saw online wasn’t entirely awful (only mostly awful). I stopped watching after about 2 episodes, but at least they had me for those two, and they wouldn’t if I wasnt able to watch the pilot early.
Sometimes this can be interesting because sometimes actors are replaced after the pilots are filmed, so when you watch a leaked pilot you can see an entirely different person as you see later on TV. This happened with the pilot of the show Reaper, which had a different… whoever the main girl is, and True Blood, where there was a different actress for Tara (who seemed less annoying, IMO). I feel bad for the directors who have to go back and re-film entire scenes of their pilots because someone in a suit didn’t like one person in them.