How about “It’s the End of the World As We Know It” by R. E. M.? I’ve tried to sing along with that in a karaoke game and even with the lyrics right in front of you, it’s hard.
Also “Hardware Store” by Weird Al is in the same category.
“We Didn’t Start the Fire.” Apparently even Billy Joel himself dreads singing it live at concerts, because if you mess up one word, everything turns into chaos.
Particularly this bit during the chorus, which is sung very quickly:
Columbus and Magellan and De Gama
Sailed upon the ocean
In a world of ignorance
With thoughts so primitive
That men were killed
With no more will
Than that they simply had the notion
But in this world of heartless men
This thing they never did.