“Pinch” or “squeal” harmonics. OK, here’s how they work [picks up guitar, watches picking hand]:
First, you have to hold the pick against the side of your first finger. If you’re holding it with the tip of your first finger and the tip of your thumb, this isn’t going to work. Put the flat of your thumb against the side of your first finger (it’s the natural place your thumb hits)–slide the pick in between.
Now…there’s maybe a 1/2 inch or less of the pick sticking out. When you’re playing regular notes, your thumb is straight–the 1st joint is almost locked flat.
When you want that extra SQUEAL, you stick out the first knuckle of your thumb just a bit–flex your thumb–which also shortens up the picking part of the pick a little. Now when you pick the note, the knuckle of your thumb will just barely touch the string right after you pick it.
As someone said–you have to be in the right spot…on my guitar there’s a spot right over the back edge (away from the neck) of the neck pickup and another just about 1/2 way between the pickups.
Once you do it, you’ll know it. Then do it a million times so you know exactly how and then practice so you can switch back and forth between regular and squeal easily. Then try it in different keys–the spot will change.
If you’re just looking for tone, that will depend on what style you’re playing and what part you’re playing. Lead is different from rhythm. Lead in any sort of rock setting will mean:
Treble 10
Mid 5-10
Bass 0
Presence 5-10
I wouldn’t use a lot of bass for playing lead–but I’m an old guy, you might not want to take my advice on that.
Someone said the Limiter is a tone control–that’s wrong. A limiter shuts down the volume peaks (“limits” the volume–duh), which might sound like a bad thing, but really it means that the rest of the note will sustain longer because the volume is evened out. So if you want those notes to hang on longer, turn the limiter up to 10!
Chorus is a vibrato-ish (“waver” or “wobble”) effect. You won’t miss it. Some day you’ll want some reverb and/or echo on your lead sound but don’t worry about that now!
Someday you’ll have a real man’s amp, with knobs that go to 11, or if you’re lucky, to 20!!! 
Princeton is a fine amp, by the way. You’re lucky to be starting with that. Some beginner’s amps sound like crap no matter where you set the knobs.