Last letter = First Letter, min 3 syllable word chain

Yokohama

acrimoniously

yesterday

youthsploitation

nicotine

establishmentarianism

mayonnaise

egalitarian

notwithstanding

glockenspiel

logarithmically

yodelburger

redacted

disproportional

liability

yellowhammer

redheaded

delusional

Lucifer

Refractive