Last letter = First Letter, min 3 syllable word chain

electrolysis

sacrilege

enneagram

methamphetamine

emetic

chariot

tenderheartedly

Yggdrasil

Llanfairpwllgwyngyllgogerychwyrndrobwllllantysiliogogogoch

hiatus

spectrophotometric

Congealing

gastropod

digitalis

stereophotographic

symbolism

mercurial

lobotomy

yuzbashi

immaculate