Last letter = First Letter, min 3 syllable word chain

salutations

sassafras

stereophonic

Charismatically

Yuppified

-“BB”-

demographically

ytterbic

cataclysmic

catechism

misandrist

typographical

-“BB”-

leatherneck

knockwurst

Territory

yellowthroated

Diaghilev

venison

notarization

neoconservatism

Manchurian