Last letter = First Letter, min 3 syllable word chain

Niggardly

-“BB”-

Ypsilanti

intellectualize

eucharistic

-“BB”-

communion

Nightmarish

holistic

cardiovascular

rambunctious

spherical

Lilliputian

-“BB”-

nasturtium

masterfully

yumminess

salient

titular

reprehensible

exausted

diastolic

chemical