My hunch about woodsmoke burning my eyes

Woodsmoke contains wood ash. Wood ash contains lye. Ergo, would the amount of lye in the smoke burn my eyes, or is it just the particulate matter? I am experiencing a long-lasting burn right now.

There are a host of different chemical irritants in wood smoke.
Some of these chemicals, such as acrolein, are potent lachrymators. Inorganic hydroxides are probably not volatile enough to be a major eye irritant in smoke.