She’s the only one with extensive training in non-powered hand-to-hand martial arts, having been a student of Iron Fist (the premier martial artist of the Marvel Universe) for quite some time. Ben knows a little judo. Reed has his spy combat training. But neither has had to use their non-powered combat skills in quite some time, while Sue’s training is more recent.
This isn’t to say that she’d win a one-on-one fight with Ben; Ben’s size, strength, and ability to take a punch would likely be more than enough compensation for Sue’s superior skill.
wolfman: I agree that Bond vs. Daredevil would be a good fight. I think that’s where you’ve got to go to get any kind of a decent matchup. Bond is going to lose more often than not to the top “normal” strength guys in both the DC and Marvel U, say Batman, Batgirl, Iron Fist, Captain America, and be more evenly matched with those that are a step down, say Nightwing, Wildcat, Huntress, Daredevil, Elektra.
Of course, any character could beat any other character depending upon who the writer is. In a fictional battle, the outcome is decided ahead of time, and the challenge is to find a way to make it interesting to the reader. The Fantastic Four are way, way outta their league going up against Galactus, but Lee and Kirby had already decided that they’d win, so they did. With the right writers, I could take down the entire JLA and JSA combined.
Likewise, we could find a way for Bond to beat Superman or Mr. Fantastic if the needs of the story dictated that he was to win. But if we go at it from the other perspective, ie, without assuming a winner in advance, I don’t see Bond putting much of a dent in any superhero with powers beyond roughly Captain America level.
If the proposal were, “How could Bond beat superheroes?” Askia’s scenarios would work a lot better. But that’s not how I read the OP.