How about a tape recorder? Keep one ready in your pocket, and if you think he is going to say something she doesn’t know about, turn it on. Play the tape for her.
I’m not a lawyer, and this might be illegal, it may not even work anyway(if she doesn’t want to believe it, she won’t).
I also think sometimes there is a fear of another failed relationship. The person continues in their current relationship regardless of whether or not the relationship is a good one just because they don’t want yet another failed relationship under their belt.